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If you have been working in the same field then is no gap in your knowledge base,so work on your GRE and TOEFL exams and apply for pHD
Also try to work on some research work in this year , related to structures - like presenting at some seminars , conferences or publishing some paper if possible these factors do count a lot for PHD applicants
Be ready with your reasons of why u felt the need to do a PHD at this point of time.
Hope that helps